Product ID:EPA TCLP VOLATILES MIX, 48143
MSDS Date:07/26/1993
FSC:6630
NIIN:00N066605
MSDS Number: CBDSQ

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

BENZENE, CHLORO-; (CHLOROBENZENE) (SARA 313) (CERCLA).

CAS: 108-90-7

RTECS: CZ0175000

Fraction By Weight: 0.1%

OSHA PEL 75 PPM

ACGIH TLV: 10 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHANE, 1,2-DICHLORO-; (1,2-DICHLOROETHANETHANE) (SARA

CAS: 107-06-2

RTECS: KI0525000

Fraction By Weight: 0.1%

OSHA PEL 50 PPM

ACGIH TLV: 10 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BENZENE, P-DICHLORO-; (1,4-DICHLOROBENZENE) (SARA 313)

CAS: 106-46-7

RTECS: CZ4550000

Fraction By Weight: 0.1%

OSHA PEL 75 PPM

ACGIH TLV: 10 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHYLENE, 1,1-DICHLORO-; (1,1-DICHLOROETHYLENE) (CERCLA).

CAS: 75-35-4

RTECS: KV9275000

Fraction By Weight: 0.1%

OSHA PEL 1 PPM

ACGIH TLV: 5 PPM;20 STEL

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHYLENE, TRICHLORO-; (ETHENE, TRICHLORO-) (SARA 313)

CAS: 79-01-6

RTECS: KX4550000

Fraction By Weight: 0.1%

OSHA PEL 100 PPM

ACGIH TLV: 50 PPM;100 STEL

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHYLENE, CHLORO-; (ETHENE, CHLORO-) (SARA 313) (CERCLA).

CAS: 75-01-4

RTECS: KU9625000

Fraction By Weight: 0.1%

OSHA PEL 1 PPM (MFR)

ACGIH TLV: 5 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313)

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 0.5%

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM;300 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA).

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 98.5%

OSHA PEL 200 PPM, S

ACGIH TLV: 200 PPM;250 STEL, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

CARBON TETRACHLORIDE; (METHANE, TETRACHLORO-) (SARA 313)

CAS: 56-23-5

RTECS: FG4900000

Fraction By Weight: 0.1%

OSHA PEL 10 PPM

ACGIH TLV: 5 PPM;10 STEL, S

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

CHLOROFORM; (METHANE, TRICHLORO-) (SARA 302/313) (CERCLA).

CAS: 67-66-3

RTECS: FS9100000

Fraction By Weight: 0.1%

OSHA PEL 50 PPM, C

ACGIH TLV: 10 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

(ORAL,RAT) 4894 MG/KG.

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 0.1%

OSHA PEL 1 PPM (MFR)

ACGIH TLV: 10 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

IARC MONOGRAPHS, SUPP, VOL 7, PG 143,

RTECS: 9999999ZZ

IARC

RTECS: 9999999ZZ

ANTIC TO BE CARCIN.

RTECS: 9999999ZZ

GRP 2B. NTP 7TH ANNUAL RPT

RTECS: 9999999ZZ

IARC MONOGRAPHS, SUPP, VOL 7, PG

RTECS: 9999999ZZ

KNOWN TO BE

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL,RAT) 5628 MG/KG (& SEE INGS).
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:HARMFUL IF INHALED. MAY BE FATAL IF
SWALLOWED. CONTAINS MATL(S) KNOWN TO STATE OF CALIFORNIA TO CAUSE
CANCER. LOW BLOOD PRESS (HYPOTENSION). DERM, BRTHG DFCLTY, HDCH,
NAUS, DIZZ, GI DISTURBS, DEPRESSE S CNS, NARCOS, LIVER/KIDNEY DMG,
RESP FAILURE, BLINDNESS, LEUKEMIA. MAY CAUSE CORNEAL INJURY. (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:BENZENE:IARC MONOGRAPHS, SUPP, VOL 7, PG
120, 1987:GRP 1. OSHA REGULATED:CFR 29 1910.1028. NTP 7TH ANNUAL
RPT ON(SUPDAT)
Effects of Overexposure:HLTH HAZ:CHLOROCARBON MATLS HAVE PRODUCED
SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE
SIMILAR EFTS IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE
CONTRAINDICATED EXCEPT FOR L IFE-SUSTAINING USES IN HUMANS
ACUTELY/CHRONICALLY EXPOS TO CHLOROCARBONS .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:FLUSH W/WATER FOR AT LST 15 MINS. CONT MD. SKIN:FLUSH
W/LG VOLS OF WATER. WASH CLTHG & SHOES BEFORE REUSING. INHAL:IMMED
MOVE TO FRESH AIR. GIVE OXYGEN IF BRTHG IS LABORED. IF BRTHG STOPS,
GIVE A RTF RESP. CONT MD. INGEST:NEVER GIVE ANYTHING BY MOUTH TO
UNCON PERS. NEVER TRY TO MAKE UNCON PERS VOMIT. GIVE 2 TBSPS OF
BAKING SODA IN GLASS OF WATER. PRESS FINGERS TO BACK OF TONGUE TO
(SUPP DATA)

Flash Point:50.0F,10.0C
Lower Limits:6%
Upper Limits:36%
Extinguishing Media:CO*2, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA &
FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:FOLLOWING TOX VAPS ARE FORMED WHEN THIS
MATL IS HEATED TO DECOMP: CARBON MONOXIDE, CARBON DIOXIDE,
FORMALDEHYDE, HYDROGEN CHLORIDE. THERMAL DECOMP PRODS(SUPDAT)

Spill Release Procedures:TAKE UP W/ABSORBENT MATERIAL. VENTILATE AREA.
ELIMINATE ALL IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN A SEALED CONTAINER IN A
FREEZER. KEEP AWAY FROM OXIDIZERS. KEEP AWAY FROM IGNITION SOURCES.
AVOID EYE/SKIN CONTACT. AVOID BREATHING VAPORS.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT &/OR UV
RADIATION MAY CAUSE THE FORMATION OF HCL &/OR PHOSGENE .

Respiratory Protection:WEAR NIOSH/MSHA APPROVED FACE MASK W/ORGANIC
VAPOR CANISTER.
Ventilation:USE ONLY IN A WELL VENTILATED AREA.
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ:MAY INCLUDE HCL &/OR PHOSGENE . FIRST AID PROC:INDUCE VOMIT.
IMMED CONT MD. EXPLAN OF CARCIN:CARCINS, 1994:KNOWN TO BE CARCIN.
HUMAN:BLOOD. BENZENE, P-CHLORO-:IARC MONOGRAPHS, SUPP, VO L 7, PG
192, 1987:GRP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC TO BE
CARCIN. ANIMAL:KIDNEY, LIVER. CARBON (ING 12)

Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:100
Vapor Density:1.1
Spec Gravity:0.79 (H*2O=1)
Evaporation Rate & Reference:>1 (ETHER=1)
Solubility in Water:100%
Appearance and Odor:CLEAR, COLORLESS LIQUID.
Percent Volatiles by Volume:1

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE,
PERCHLORIC ACID, ALUMINUM & MAGNESIUM, METALS.
Hazardous Decomposition Products:PHOSGENE . CARBON MONOXIDE, CARBON
DIOXIDE, FORMALDEHYDE, HYDROGEN CHLORIDE.

Waste Disposal Methods:COMPLY W/ALL APPLICABLE FEDERAL, STATE OR LOCAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.